Preheat oven to 350°F. Place 30 paper liners in 2 1/2-inch diameter muffin cups.
Combine cake mix, buttermilk, coffee, and eggs in mixing bowl. Beat at low speed of electric mixer until dry ingredients are moistened. Beat at high speed 1 minute more, scraping down sides. Spoon batter into prepared muffin cups, filling each three-fourths full.
Stir together flour, brown sugar, and cinnamon; cut in butter with fork until crumbly. Stir in pecans, mixing well. Spoon mixture evenly over batter in each muffin cup.
Bake 25 to 30 minutes or until a wooden toothpick inserted in center comes out clean. Cool in pans on wire rack 5 minutes. Remove cupcakes from pans; cool completely before serving.
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